ICAR Research Data Repository for Knowledge Management
ZnCl2-catalyzed Ferrier reaction; synthesis of 2,3-unsaturated 1-O-glucopyranosides of allylic, benzylic and tertiary alcohols
IR@CSIR-CFTRI
View Archive Info| Field | Value | |
| Relation |
http://ir.cftri.com/1491/
TL_01_03 |
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| Title |
ZnCl2-catalyzed Ferrier reaction; synthesis of 2,3-unsaturated 1-O-glucopyranosides of allylic, benzylic and tertiary alcohols
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| Creator |
Bettadaiah, B. K.
Srinivas, P. |
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| Subject |
24 Organic Chemistry
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| Description |
Tertiary, allylic and benzylic alcohols react with 3,4,6-tri-O-acetyl-D-glucal in dichloromethane at 25°C in the presence of ZnCl2 to afford the corresponding 2,3-unsaturated-1-O-glucopyranoside acetates in 65–91% yields, with selective formation of the α-anomer.
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| Date |
2003
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Language |
en
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| Rights |
—
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| Identifier |
http://ir.cftri.com/1491/1/Tetrahedron_Letters_44_%282003%29_7257-7259.pdf
Bettadaiah, B. K. and Srinivas, P. (2003) ZnCl2-catalyzed Ferrier reaction; synthesis of 2,3-unsaturated 1-O-glucopyranosides of allylic, benzylic and tertiary alcohols. Tetrahedron Letters, 44. pp. 7257-7259. |
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