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Guttiferic acid, a novel rearrangement product from minor chromenoxanthone pigments of Garcinia morella Desr.

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Relation http://ir.cftri.com/1862/
MRC-01-07
 
Title Guttiferic acid, a novel rearrangement product from minor chromenoxanthone pigments of Garcinia morella Desr.
 
Creator Rajagopal Rao, D.
Gurudutt, K. N.
Mamatha, S.
Jagan Mohan Rao, L.
 
Subject 02 Alkaloids Chemistry
10 Plants
 
Description Morellic and isomorellic acids (2 and 3), present in the seed coat as well as resinous exudate of Garcinia morella Desr., are geometric isomers and structurally related to morellin (1), the major chromenoxanthone pigment. Both form crystalline complexes with pyridine and afford guttiferic acid (7), a novel skeletal rearrangement product, when heated with mild alkali. Structure of the latter has been deduced mainly by a comparative study of 1H and 13C NMR spectra of methyl morellate (5), methyl-O-methyl morellate (6), guttiferic acid (7) and dimethyl guttiferate (8).
 
Date 2007
 
Type Article
PeerReviewed
 
Format application/pdf
 
Language en
 
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Identifier http://ir.cftri.com/1862/1/Magn._Reson._Chem._2007%3B_45_578-582.pdf
Rajagopal Rao, D. and Gurudutt, K. N. and Mamatha, S. and Jagan Mohan Rao, L. (2007) Guttiferic acid, a novel rearrangement product from minor chromenoxanthone pigments of Garcinia morella Desr. Magnetic resonance in chemistry : MRC, 45 (7). pp. 578-82. ISSN 0749-1581