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Field | Value |
Title | Selenium-bridged clusters - synthesis and structural characterization of cp2mo2fe2(mu(4)-se)(mu(3)-se)2(co)6 |
Names |
MATHUR, P
(author) HOSSAIN, MM (author) RHEINGOLD, AL (author) |
Date Issued | 1993 (iso8601) |
Abstract | Thermolysis of Fe2(CO)6{mu-SeC(Ph)=C(H)Se} (1) and Cp2Mo2(CO)6 (2) yields the new cluster Cp2Mo2Fe2(mu4-Se)(mu3-Se)2(CO)6 (3) and Cp2Mo2(CO)4(PhCCH) (4). Structural characterization of 3 shows an unusual mu4-Se ligand bridging the two wing-tip Fe atoms and the two hinge Mo atoms of the Mo2Fe2 butterfly-tetrahedron core. |
Genre | Note |
Topic | metal multiple bonds |
Identifier | 0276-7333 |
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