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| Field | Value |
| Title | Formation of mixed Fe/W/S complexes bearing oxo and acetylide ligands : synthesis and characterization of [(eta(5)-C5Me5)W2Fe2(CO)(6)(O)(2)(mu-O)(mu(3)-S)(2) (eta(1):eta(2)-CCR)] (R=Ph, (Me)C=CH2) and [(eta(5)-C5Me5)W2Fe2(CO)(6)(O)(mu-O)(mu(3)-S)(2) (eta(1):eta(2)-CCR)(eta(2)-RCCH)] (R=Ph, (Me)C=CH2) |
| Names |
MATHUR, P
(author) BHUNIA, AK (author) MOBIN, SM (author) |
| Date Issued | 2004 (iso8601) |
| Abstract | Reaction of the acetylide-bearing oxo-peroxo complex [(eta(5)-C5Me5) W(O-2)(O) (eta(1)-CCR)] (R = Ph, (Me) C = CH2) with [Fe2W(CO)(10)(mu(3)-S)(2)] yielded [(eta(5)-C5Me5) W2Fe2(CO)(6)(O)(2)(mu-O)(mu(3)-S)(2)(eta(1):eta(2)- CCR)]. When the reaction was carried out in presence of free acetylene, RC = CH (R = Ph, (Me) C = CH2), clusters [(eta(5)-C5Me5) W2Fe2(CO)(6)(O)(mu-O)(mu(3)-S)(2)(eta(1): eta(2)- CCR)(eta(2)-RCCH)] were obtained. Structures of one of each type of cluster were determined by single crystal X-ray diffraction methods. |
| Genre | Article; Proceedings Paper |
| Topic | structural characterization |
| Identifier | 1040-7278 |
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