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Intramolecularly coordinated organoselenium darivatives : syntheses, structure and reactivity

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Title Intramolecularly coordinated organoselenium darivatives : syntheses, structure and reactivity
 
Creator PANDA, A
MUGESH, G
SINGH, HB
BUTCHER, RJ
 
Subject chiral selenium-compounds
monomeric selenolato complexes
macrocyclic schiff-base
x-ray structure
asymmetric methoxyselenenylation
sigmatropic rearrangement
diferrocenyl diselenides
organic-synthesis
camphorselenenyl sulfate
addition-reactions
intramolecular nonbonded interactions
ligands
organic synthesis
mocvd
organochalcogens
selenium macrocycle
 
Description Although intramolecularly coordinated organotellurium derivatives have been extensively studied in recent years, the analogous derivatives of selenium have received little attention. We have recently started work on syntheses, structures and reactivity of intramolecularly coordinated organoselenium compounds. The synthesis of these compounds makes extensive use of the ortho-lithiation reaction followed by insertion of selenium into Li-C bond.
 
Publisher GORDON BREACH PUBLISHING, TAYLOR & FRANCIS GROUP
 
Date 2011-10-22T18:51:22Z
2011-12-15T09:10:45Z
2011-10-22T18:51:22Z
2011-12-15T09:10:45Z
2001
 
Type Article; Proceedings Paper
 
Identifier PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS,171,187-205
1042-6507
http://dx.doi.org/10.1080/10426500108046633
http://dspace.library.iitb.ac.in/xmlui/handle/10054/14963
http://hdl.handle.net/100/1641
 
Source 8th International Conference on the Chemistry of Selenium and Tellurium (ICCST-8),SAO PAULO STATE, BRAZIL,AUG 06-11, 2000
 
Language English