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Formation of one-dimensional water inside an organic solid: supramolecular architectures derived by the interaction of aminobenzoic acids with nitrogen bases and h2so4

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Title Formation of one-dimensional water inside an organic solid: supramolecular architectures derived by the interaction of aminobenzoic acids with nitrogen bases and h2so4
 
Creator BANERJEE, S
MURUGAVEL, R
 
Subject center-dot-n
substituted benzoic-acids
o hydrogen-bonds
framework metal phosphates
ray crystal-structures
carboxylic-acids
molecular cocrystals
2-aminobenzoic acid
3-aminobenzoic acid
3,5-dinitrobenzoic acid
 
Description Three different organic supramolecular architectures derived from 2- and 3-aminobenzoic acids are reported. 3-Aminobenzoic acid (3-ABA-H) forms complexes with 2-aminopyridine (2-AP) and 1,4-diazabicyclo[2,2,2]-octane (DABCO) to yield [(3-ABA)(2-AP-H)] (1) and [(3-ABA)(DABCO-H)(H2O)(2)] (2), respectively. 2-Aminobenzoic acid (2-ABA-H), on the other hand, interacts with sulfuric acid in the presence of V2O5 to yield [(2-ABA-H-2)(4)(HSO4)(2)-(SO4)(H2O)] (3). Compounds 1-3 have been obtained as single crystals and characterized by elemental analysis, IR and H-1 NMR spectroscopy, and single-crystal X-ray diffraction techniques. Compound 1 crystallizes in the monoclinic space group P2(1)/c [alpha = 9.6455(5) Angstrom, b = 10.9229(7) Angstrom, c = 11.976(2) Angstrom, beta = 112.932(7)degrees, R1 = 0.0363]. It is an infinite two-dimensional layered polymer in which the carboxylic acid hydrogen is transferred to the pyridine nitrogen. Compound 2 crystallizes in the monoclinic space group Cc [alpha = 14.2950(9), b = 11.7660(7), c = 9.813(l) Angstrom, beta = 116.214(7)degrees, R1 = 0.0492], in which one of the DABCO nitrogens is protonated by accepting the proton of the carboxylic acid. The two water molecules present in the asymmetric part of the unit cell of 2 form an unusual assembly of water to form a one-dimensional polymeric chain through hydrogen bonding. Compound 3 crystallizes in the triclinic space group P (1) over bar [alpha = 7.470(1), b = 11.128(l), c = 22.552(2) Angstrom, alpha = 85.075(7)degrees, beta = 88.712(9)degrees, gamma = 72.509(8)degrees, R1 = 0.0573]. A number of N-H...O, O-H...O, and/or N-H...N hydrogen bonds are prevalent in the structures of 1-3, resulting in the formation a two- or three-dimensional supramolecular architecture in these compounds.
 
Publisher AMER CHEMICAL SOC
 
Date 2011-10-13T23:01:58Z
2011-12-15T09:16:03Z
2011-10-13T23:01:58Z
2011-12-15T09:16:03Z
2004
 
Type Review
 
Identifier CRYSTAL GROWTH & DESIGN,4(3)545-552
1528-7483
http://dx.doi.org/10.1021/cg034229c
http://dspace.library.iitb.ac.in/xmlui/handle/10054/13872
http://hdl.handle.net/100/2974
 
Language en