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Rings, chains and cages in metal phosphate chemistry: the interdependence and possible interconversion between various structural forms

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Title Rings, chains and cages in metal phosphate chemistry: the interdependence and possible interconversion between various structural forms
 
Creator MURUGAVEL, R
GOGOI, N
 
Subject metal phosphates
clusters
structural studies
tert-butyl phosphate
purple acid-phosphatases
diiron(iii) complexes
auxiliary ligands
iron(iii) complex
ancillary ligands
crystal-structure
model compounds
core
di
 
Description Our endeavour to build soluble model compounds of basic building blocks in zeolite structures have resulted in a plethora of main group and transition metal phosphate complexes. Many of these complexes show highly intriguing and novel structural features. Careful examination of the core structures allowed us to rationalize the interdependence between the different structural types and visualize their plausible pathway of formation. Due to the high reactivity and short life span of the intermediates it has not been possible to characterize many intermediates. However, the common structural features present in the isolated products drive us to arrive at a plausible mechanism. Further investigation and isolation of other structural types will definitely provide more credential to these hypotheses and help us to solve the zeolite jigsaw. (C) 2009 Elsevier B. V. All rights reserved.
 
Publisher ELSEVIER SCIENCE SA
 
Date 2011-10-13T18:54:40Z
2011-12-15T09:16:04Z
2011-10-13T18:54:40Z
2011-12-15T09:16:04Z
2010
 
Type Review
 
Identifier JOURNAL OF ORGANOMETALLIC CHEMISTRY,695(7)916-924
0022-328X
http://dx.doi.org/10.1016/j.jorganchem.2009.10.046
http://dspace.library.iitb.ac.in/xmlui/handle/10054/13820
http://hdl.handle.net/100/2977
 
Language en