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Expanding the diversity of polycyclic aromatics through a suzuki-miyaura cross-coupling strategy

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Title Expanding the diversity of polycyclic aromatics through a suzuki-miyaura cross-coupling strategy
 
Creator KOTHA, S
LAHIRI, K
 
Subject c-c coupling
polycycles
amino acids
palladium
boron
amino-acid derivatives
simple synthetic approach
ring-closing metathesis
diels-alder approach
arylboronic acids
potassium aryl
9,10-diarylanthracene derivatives
phenylalanine peptides
organic-synthesis
palladium
 
Description In recent years, Pd-catalyzed Suzuki-Miyaura (SM) cross-coupling reactions have revolutionized approaches to carbon-carbon bond formation. We have studied the application of SM coupling with several (ca. 16) complex molecular structures of particular relevance to scientists working at the interfaces of chemistry, biology, and materials sciences. In this regard, various structurally or biologically important polycyclic molecules (e.g., benzocrowns, C-3-symmetric molecules, 9,10-disubstituted anthracenes, and sulfones) and unusual amino acid derivatives have been modified by this reaction, while it has also been shown that allylation of aromatics through the use of a commercially available boronic acid ester by SM coupling under CsF/Pd-0 conditions is feasible. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006).
 
Publisher WILEY-V C H VERLAG GMBH
 
Date 2011-10-12T12:18:39Z
2011-12-15T09:16:07Z
2011-10-12T12:18:39Z
2011-12-15T09:16:07Z
2007
 
Type Review
 
Identifier EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,(8)1221-1236
1434-193X
http://dx.doi.org/10.1002/ejoc.200600519
http://dspace.library.iitb.ac.in/xmlui/handle/10054/13768
http://hdl.handle.net/100/3003
 
Language en