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A diversity-oriented approach to diphenylalkanes by strategic utilization of [2+2+2] cyclotrimerization, cross-enyne metathesis and diels-alder reaction

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Title A diversity-oriented approach to diphenylalkanes by strategic utilization of [2+2+2] cyclotrimerization, cross-enyne metathesis and diels-alder reaction
 
Creator KOTHA, S
KHEDKAR, P
 
Subject cyclotrimerization
diels-alder reaction
diphenylalkanes
diversity-oriented approach
metathesis
catalyzed alkyne cyclotrimerization
polysubstituted benzene-derivatives
transition-metal-complexes
3 unsymmetrical alkynes
boron temporary tether
olefin-metathesis
carbonyl-compounds
organic-synthesis
terminal alkynes
nickel-complexes
 
Description A novel and efficient approach towards the synthesis of polysubstituted diphenylalkane derivatives have been demonstrated using a strategic combination of [2+2+2] cyclotrimerization, ethylene cross-enyne metathesis and Diels-Alder reaction as key steps. The strategy involves the stepwise functionalization of acetylenic termini of alpha,omega-diyne scaffold to build functionalized aromatic units. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
 
Publisher WILEY-V C H VERLAG GMBH
 
Date 2011-10-12T13:41:34Z
2011-12-15T09:16:09Z
2011-10-12T13:41:34Z
2011-12-15T09:16:09Z
2009
 
Type Review
 
Identifier EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,(5)730-738
1434-193X
http://dx.doi.org/10.1002/ejoc.200800924
http://dspace.library.iitb.ac.in/xmlui/handle/10054/13788
http://hdl.handle.net/100/3026
 
Language en