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Synthesis of novel quinone-amino acid hybrids via cross-enyne metathesis and diels-alder reaction as key steps

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Title Synthesis of novel quinone-amino acid hybrids via cross-enyne metathesis and diels-alder reaction as key steps
 
Creator KOTHA, S
MANDAL, K
BANERJEE, S
MOBIN, SM
 
Subject quinone-amino acid hybrids
cross-enyne metathesis
cycloaddition
fullerenes
natural-product hybrids
ring-closing metathesis
olefin-metathesis
stereoselective-synthesis
1,3-diene synthesis
(s,s)-2,7-diaminosuberic acid
annonaceous acetogenins
biological evaluation
asymmetric-synthesis
efficient synthesis
 
Description A "Building Block Approach" for the synthesis of various quinone-amino acid hybrids through ethylene cross-enyne metathesis and Diels-Alder reaction as key steps is described. A library of comformationally constrained quinone-based phenylalanine derivatives and dicarba analogs of cystine have been generated starting from a common precursor using Grubbs' catalysts. This methodology has also been extended for the synthesis of fullerene-based dicarba analogs of cystine. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007).
 
Publisher WILEY-V C H VERLAG GMBH
 
Date 2011-10-13T19:38:14Z
2011-12-15T09:16:09Z
2011-10-13T19:38:14Z
2011-12-15T09:16:09Z
2007
 
Type Review
 
Identifier EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,(8)1244-1255
1434-193X
http://dx.doi.org/10.1002/ejoc.200600970
http://dspace.library.iitb.ac.in/xmlui/handle/10054/13832
http://hdl.handle.net/100/3028
 
Language en