Synthetic organoselenium compounds as antioxidants: glutathione peroxidase activity
DSpace at IIT Bombay
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Title |
Synthetic organoselenium compounds as antioxidants: glutathione peroxidase activity
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Creator |
MUGESH, G
SINGH, HB |
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Subject |
crystal-structure
model derivatives diselenides resolution chemistry mimetics ebselen |
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Description |
Organoselenium compounds find applications in organic synthesis, materials synthesis, ligand chemistry and biologically relevant processes. This review deals with the use of various synthetic organoselenium compounds as mimics of glutathione peroxidase (GPx), a selenoenzyme which catalyses the reduction of a variety of hydroperoxides and protects the cell membranes from oxidative damage. The mechanism by which these compounds catalyse the reduction of peroxides is also reviewed. The cyclic selenenamides and diselenides with suitably positioned substituents exert their catalytic activity by a mechanism similar to that of the natural enzyme.
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Publisher |
ROYAL SOC CHEMISTRY
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Date |
2011-10-13T23:35:42Z
2011-12-15T09:16:14Z 2011-10-13T23:35:42Z 2011-12-15T09:16:14Z 2000 |
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Type |
Review
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Identifier |
CHEMICAL SOCIETY REVIEWS,29(5)347-357
0306-0012 http://dx.doi.org/10.1039/a908114c http://dspace.library.iitb.ac.in/xmlui/handle/10054/13880 http://hdl.handle.net/100/3065 |
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Language |
en
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