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Di-tert-butylphosphate complexes of Mn(II) and Cu(II) as single-source precursors for metal phosphate materials

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Field Value
 
Title Di-tert-butylphosphate complexes of Mn(II) and Cu(II) as single-source precursors for metal phosphate materials
 
Creator MURUGAVEL, R
SATHIYENDIRAN, M
 
Subject routes
orthosilicate
oxides
model
 
Description Octahedral Mn(II) and Cu(II) di-tert-butylphosphate (L) complexes [ML2(imz)(4)] have been synthesized and characterized using IR, UV-vis, luminescence, and EPR spectroscopy and single crystal X-ray diffraction studies. Thermal decomposition of both the complexes (probed by TGA, DTA, and DSC) indicate stepwise elimination of iso-butene. imidazole and water to finally yield the respective ceramic materials Mn(PO3)(2) or Cu(PO3)(2).
 
Publisher CHEMICAL SOC JAPAN
 
Date 2011-07-20T07:52:59Z
2011-12-26T12:51:22Z
2011-12-27T05:34:26Z
2011-07-20T07:52:59Z
2011-12-26T12:51:22Z
2011-12-27T05:34:26Z
2001
 
Type Article
 
Identifier CHEMISTRY LETTERS, (1), 84-85
0366-7022
http://dx.doi.org/10.1246/cl.2001.84
http://dspace.library.iitb.ac.in/xmlui/handle/10054/5400
http://hdl.handle.net/10054/5400
 
Language en