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Synthesis and molecular structure of 1,3-di-tert-butyl-2,4-bis(cyclodipentadienyl)iron(II) 1,3,2,4-diazadiphosphetidine, [Fe(eta(5)-C5H4)(2)((PNBu)-Bu-t)(2)]

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Title Synthesis and molecular structure of 1,3-di-tert-butyl-2,4-bis(cyclodipentadienyl)iron(II) 1,3,2,4-diazadiphosphetidine, [Fe(eta(5)-C5H4)(2)((PNBu)-Bu-t)(2)]
 
Creator BALAKRISHNA, MS
MAGUE, JT
 
Subject ring-opening polymerization
phosph(iii)azane macrocycle
reversible conversion
catalytic-activity
complexes
coordination
crystal
ligands
cyclodiphosphazane
chemistry
 
Description The reaction of the dichlorocyclodiphosphazane (also called dichlorodiazadiphosphetidine), [ClP(mu-(NBu)-Bu-t)](2), with in situ generated ferrocene dilithiate in a 1:1 molar ratio affords the first metallocene derivative of a diazadiphosphetidine, 1,3-di-tert-butyl-2,4-bis(cyclopentadienyl)iron(II) 1,3,2,4-diazadiphosphetidine, [Fe(eta(5)-C5H4)(2)((PNBu)-Bu-t)(2)], in good yield.
 
Publisher AMER CHEMICAL SOC
 
Date 2011-07-14T23:31:26Z
2011-12-26T12:49:07Z
2011-12-27T05:34:51Z
2011-07-14T23:31:26Z
2011-12-26T12:49:07Z
2011-12-27T05:34:51Z
2007
 
Type Article
 
Identifier ORGANOMETALLICS, 26(18), 4677-4679
0276-7333
http://dx.doi.org/10.1021/om700423h
http://dspace.library.iitb.ac.in/xmlui/handle/10054/4095
http://hdl.handle.net/10054/4095
 
Language en