Synthesis and molecular structure of 1,3-di-tert-butyl-2,4-bis(cyclodipentadienyl)iron(II) 1,3,2,4-diazadiphosphetidine, [Fe(eta(5)-C5H4)(2)((PNBu)-Bu-t)(2)]
DSpace at IIT Bombay
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Title |
Synthesis and molecular structure of 1,3-di-tert-butyl-2,4-bis(cyclodipentadienyl)iron(II) 1,3,2,4-diazadiphosphetidine, [Fe(eta(5)-C5H4)(2)((PNBu)-Bu-t)(2)]
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Creator |
BALAKRISHNA, MS
MAGUE, JT |
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Subject |
ring-opening polymerization
phosph(iii)azane macrocycle reversible conversion catalytic-activity complexes coordination crystal ligands cyclodiphosphazane chemistry |
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Description |
The reaction of the dichlorocyclodiphosphazane (also called dichlorodiazadiphosphetidine), [ClP(mu-(NBu)-Bu-t)](2), with in situ generated ferrocene dilithiate in a 1:1 molar ratio affords the first metallocene derivative of a diazadiphosphetidine, 1,3-di-tert-butyl-2,4-bis(cyclopentadienyl)iron(II) 1,3,2,4-diazadiphosphetidine, [Fe(eta(5)-C5H4)(2)((PNBu)-Bu-t)(2)], in good yield.
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Publisher |
AMER CHEMICAL SOC
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Date |
2011-07-14T23:31:26Z
2011-12-26T12:49:07Z 2011-12-27T05:34:51Z 2011-07-14T23:31:26Z 2011-12-26T12:49:07Z 2011-12-27T05:34:51Z 2007 |
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Type |
Article
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Identifier |
ORGANOMETALLICS, 26(18), 4677-4679
0276-7333 http://dx.doi.org/10.1021/om700423h http://dspace.library.iitb.ac.in/xmlui/handle/10054/4095 http://hdl.handle.net/10054/4095 |
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Language |
en
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