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Tetranuclear rhodium(I) macrocycle containing cyclodiphosphazane [Rh-2(mu-Cl)(2)(CO)(2){((BuNP)-Bu-t(OC6H4OMe-o))(2)-kappa P](2) and its reversible conversion into trans-[Rh(CO)Cl{((BuNP)-Bu-t(OC6H4OMe-o))(2-)kappa P}(2)]

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Title Tetranuclear rhodium(I) macrocycle containing cyclodiphosphazane [Rh-2(mu-Cl)(2)(CO)(2){((BuNP)-Bu-t(OC6H4OMe-o))(2)-kappa P](2) and its reversible conversion into trans-[Rh(CO)Cl{((BuNP)-Bu-t(OC6H4OMe-o))(2-)kappa P}(2)]
 
Creator CHANDRASEKARAN, P
MAGUE, JT
BALAKRISHNA, MS
 
Subject x-ray structures
complexes
metallomacrocycles
platinum(ii)
diphosphazanes
palladium(ii)
derivatives
ligands
pd(ii)
 
Description The 1:1 reaction between cis-[(BuNP)-Bu-t(OC6H4OMe-o)](2) (2) and [Rh(mu-Cl)(CO)(2)](2) affords novel tetranuclear rhodium(l) macrocycle (3) containing two cyclodiphosphazanes bridged by two [Rh(mu-Cl)(CO)](2) moieties, whereas the corresponding 4:1 reaction affords trans-[Rh(CO)Cl-{((BuNP)-Bu-t(OC6H4OMe-o))(2)-kappa P}2] (4).
 
Publisher AMER CHEMICAL SOC
 
Date 2011-07-15T01:51:55Z
2011-12-26T12:49:10Z
2011-12-27T05:34:57Z
2011-07-15T01:51:55Z
2011-12-26T12:49:10Z
2011-12-27T05:34:57Z
2005
 
Type Article
 
Identifier ORGANOMETALLICS, 24(15), 3780-3783
0276-7333
http://dx.doi.org/10.1021/om0502537
http://dspace.library.iitb.ac.in/xmlui/handle/10054/4119
http://hdl.handle.net/10054/4119
 
Language en