Tetranuclear rhodium(I) macrocycle containing cyclodiphosphazane [Rh-2(mu-Cl)(2)(CO)(2){((BuNP)-Bu-t(OC6H4OMe-o))(2)-kappa P](2) and its reversible conversion into trans-[Rh(CO)Cl{((BuNP)-Bu-t(OC6H4OMe-o))(2-)kappa P}(2)]
DSpace at IIT Bombay
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Title |
Tetranuclear rhodium(I) macrocycle containing cyclodiphosphazane [Rh-2(mu-Cl)(2)(CO)(2){((BuNP)-Bu-t(OC6H4OMe-o))(2)-kappa P](2) and its reversible conversion into trans-[Rh(CO)Cl{((BuNP)-Bu-t(OC6H4OMe-o))(2-)kappa P}(2)]
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Creator |
CHANDRASEKARAN, P
MAGUE, JT BALAKRISHNA, MS |
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Subject |
x-ray structures
complexes metallomacrocycles platinum(ii) diphosphazanes palladium(ii) derivatives ligands pd(ii) |
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Description |
The 1:1 reaction between cis-[(BuNP)-Bu-t(OC6H4OMe-o)](2) (2) and [Rh(mu-Cl)(CO)(2)](2) affords novel tetranuclear rhodium(l) macrocycle (3) containing two cyclodiphosphazanes bridged by two [Rh(mu-Cl)(CO)](2) moieties, whereas the corresponding 4:1 reaction affords trans-[Rh(CO)Cl-{((BuNP)-Bu-t(OC6H4OMe-o))(2)-kappa P}2] (4).
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Publisher |
AMER CHEMICAL SOC
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Date |
2011-07-15T01:51:55Z
2011-12-26T12:49:10Z 2011-12-27T05:34:57Z 2011-07-15T01:51:55Z 2011-12-26T12:49:10Z 2011-12-27T05:34:57Z 2005 |
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Type |
Article
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Identifier |
ORGANOMETALLICS, 24(15), 3780-3783
0276-7333 http://dx.doi.org/10.1021/om0502537 http://dspace.library.iitb.ac.in/xmlui/handle/10054/4119 http://hdl.handle.net/10054/4119 |
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Language |
en
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