Total Syntheses of All Stereoisomers of Phenatic Acid B
DSpace at IIT Bombay
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Title |
Total Syntheses of All Stereoisomers of Phenatic Acid B
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Creator |
FERNANDES, RA
CHOWDHURY, AK |
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Subject |
asymmetric dihydroxylation
claisen rearrangement polyvalent iodine chemistry |
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Description |
The total syntheses of all stereoisomers of phenatic acid B and determination of their absolute configuration are described. The synthetic strategy is based on all efficient combination of the Sharpless asymmetric dihydroxylation, the Johnson-Claisen rearrangement, and hydroboration-oxidation. It involves 11-12 steps and overall yield of 5-8%.
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Publisher |
AMER CHEMICAL SOC
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Date |
2011-07-15T03:06:23Z
2011-12-26T12:49:12Z 2011-12-27T05:35:00Z 2011-07-15T03:06:23Z 2011-12-26T12:49:12Z 2011-12-27T05:35:00Z 2009 |
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Type |
Article
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Identifier |
JOURNAL OF ORGANIC CHEMISTRY, 74(22), 8826-8829
0022-3263 http://dx.doi.org/10.1021/jo901927w http://dspace.library.iitb.ac.in/xmlui/handle/10054/4139 http://hdl.handle.net/10054/4139 |
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Language |
en
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