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Total Syntheses of All Stereoisomers of Phenatic Acid B

DSpace at IIT Bombay

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Field Value
 
Title Total Syntheses of All Stereoisomers of Phenatic Acid B
 
Creator FERNANDES, RA
CHOWDHURY, AK
 
Subject asymmetric dihydroxylation
claisen rearrangement
polyvalent iodine
chemistry
 
Description The total syntheses of all stereoisomers of phenatic acid B and determination of their absolute configuration are described. The synthetic strategy is based on all efficient combination of the Sharpless asymmetric dihydroxylation, the Johnson-Claisen rearrangement, and hydroboration-oxidation. It involves 11-12 steps and overall yield of 5-8%.
 
Publisher AMER CHEMICAL SOC
 
Date 2011-07-15T03:06:23Z
2011-12-26T12:49:12Z
2011-12-27T05:35:00Z
2011-07-15T03:06:23Z
2011-12-26T12:49:12Z
2011-12-27T05:35:00Z
2009
 
Type Article
 
Identifier JOURNAL OF ORGANIC CHEMISTRY, 74(22), 8826-8829
0022-3263
http://dx.doi.org/10.1021/jo901927w
http://dspace.library.iitb.ac.in/xmlui/handle/10054/4139
http://hdl.handle.net/10054/4139
 
Language en