Total Synthesis of (+)-Demethoxycardinalin 3
DSpace at IIT Bombay
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Title |
Total Synthesis of (+)-Demethoxycardinalin 3
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Creator |
FERNANDES, RA
MULAY, SV |
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Subject |
pictet-spengler cyclization
pyranonaphthoquinone antibiotics asymmetric dihydroxylation dermocybe cardinalis crisamicin-a micromonospora (+)-kalafungin derivatives annulation complexes |
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Description |
The total synthesis of (+)-demethoxycardmalm 3 is described The synthetic strategy features the synthesis of dimerie Fischer carbene and us use in a biduectional Doi/ benzamulation reaction to set the dimerie structure of the cardmalms. The oxa-picict-Spengler reaction was used to construct the pyran rings The synthesis as completed in seven steps and an overall yield of 7%
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Publisher |
AMER CHEMICAL SOC
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Date |
2011-07-15T03:09:11Z
2011-12-26T12:49:12Z 2011-12-27T05:35:00Z 2011-07-15T03:09:11Z 2011-12-26T12:49:12Z 2011-12-27T05:35:00Z 2010 |
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Type |
Article
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Identifier |
JOURNAL OF ORGANIC CHEMISTRY, 75(20), 7029-7032
0022-3263 http://dx.doi.org/10.1021/jo101628m http://dspace.library.iitb.ac.in/xmlui/handle/10054/4140 http://hdl.handle.net/10054/4140 |
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Language |
en
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