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Total Synthesis of (+)-Demethoxycardinalin 3

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Field Value
 
Title Total Synthesis of (+)-Demethoxycardinalin 3
 
Creator FERNANDES, RA
MULAY, SV
 
Subject pictet-spengler cyclization
pyranonaphthoquinone antibiotics
asymmetric dihydroxylation
dermocybe cardinalis
crisamicin-a
micromonospora
(+)-kalafungin
derivatives
annulation
complexes
 
Description The total synthesis of (+)-demethoxycardmalm 3 is described The synthetic strategy features the synthesis of dimerie Fischer carbene and us use in a biduectional Doi/ benzamulation reaction to set the dimerie structure of the cardmalms. The oxa-picict-Spengler reaction was used to construct the pyran rings The synthesis as completed in seven steps and an overall yield of 7%
 
Publisher AMER CHEMICAL SOC
 
Date 2011-07-15T03:09:11Z
2011-12-26T12:49:12Z
2011-12-27T05:35:00Z
2011-07-15T03:09:11Z
2011-12-26T12:49:12Z
2011-12-27T05:35:00Z
2010
 
Type Article
 
Identifier JOURNAL OF ORGANIC CHEMISTRY, 75(20), 7029-7032
0022-3263
http://dx.doi.org/10.1021/jo101628m
http://dspace.library.iitb.ac.in/xmlui/handle/10054/4140
http://hdl.handle.net/10054/4140
 
Language en