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SILVER(I) OXIDE CATALYZED OXIDATION OF ORTHO-ALLYLPHENOLS AND ORTHO-(1-PROPENYL)PHENOLS

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Title SILVER(I) OXIDE CATALYZED OXIDATION OF ORTHO-ALLYLPHENOLS AND ORTHO-(1-PROPENYL)PHENOLS
 
Creator IYER, MR
TRIVEDI, GK
 
Description The oxidation behavior of o-alkenylphenols towards a one-electron transfer agent, silver(I) oxide, was studied. Oxidation of an o-(1-alkenyl)phenol yields a dimeric product via the intermediacy of a quinonemethide radical. However, in the case of an o-(2-alkenyl)phenol where the gamma-carbon bears substituents, a 2H-chromene is the product. During the course of this study, carpanone, a naturally-occurring lignan, was synthesized.
 
Publisher CHEMICAL SOC JAPAN
 
Date 2011-07-20T09:08:51Z
2011-12-26T12:51:24Z
2011-12-27T05:35:41Z
2011-07-20T09:08:51Z
2011-12-26T12:51:24Z
2011-12-27T05:35:41Z
1992
 
Type Article
 
Identifier BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 65(6), 1662-1664
0009-2673
http://dx.doi.org/10.1246/bcsj.65.1662
http://dspace.library.iitb.ac.in/xmlui/handle/10054/5421
http://hdl.handle.net/10054/5421
 
Language en