SILVER(I) OXIDE CATALYZED OXIDATION OF ORTHO-ALLYLPHENOLS AND ORTHO-(1-PROPENYL)PHENOLS
DSpace at IIT Bombay
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Title |
SILVER(I) OXIDE CATALYZED OXIDATION OF ORTHO-ALLYLPHENOLS AND ORTHO-(1-PROPENYL)PHENOLS
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Creator |
IYER, MR
TRIVEDI, GK |
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Description |
The oxidation behavior of o-alkenylphenols towards a one-electron transfer agent, silver(I) oxide, was studied. Oxidation of an o-(1-alkenyl)phenol yields a dimeric product via the intermediacy of a quinonemethide radical. However, in the case of an o-(2-alkenyl)phenol where the gamma-carbon bears substituents, a 2H-chromene is the product. During the course of this study, carpanone, a naturally-occurring lignan, was synthesized.
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Publisher |
CHEMICAL SOC JAPAN
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Date |
2011-07-20T09:08:51Z
2011-12-26T12:51:24Z 2011-12-27T05:35:41Z 2011-07-20T09:08:51Z 2011-12-26T12:51:24Z 2011-12-27T05:35:41Z 1992 |
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Type |
Article
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Identifier |
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 65(6), 1662-1664
0009-2673 http://dx.doi.org/10.1246/bcsj.65.1662 http://dspace.library.iitb.ac.in/xmlui/handle/10054/5421 http://hdl.handle.net/10054/5421 |
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Language |
en
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