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KINETICS OF DIACETYLENE POLYMERIZATION - AN FT-RAMAN STUDY

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Title KINETICS OF DIACETYLENE POLYMERIZATION - AN FT-RAMAN STUDY
 
Creator KAMATH, M
KIM, WH
LI, L
KUMAR, J
TRIPATHY, S
BABU, KN
TALWAR, SS
 
Subject solid-state polymerization
polydiacetylene
scattering
films
1,4-bis(3-quinolyl)-1,3-butadiyne
spectroscopy
dependence
crystal
spectra
 
Description Changes in the FT-Raman spectrum of 1,4-bis(3-quinolyl)buta-1,3-diyne (DQ) as a function of gamma-ray dosage is used to monitor the degree of monomer to polymer conversion in a solid-state topochemical polymerization reaction. The relative intensities of the characteristic C=C peaks in the nonresonant FT-Raman spectra provide a nondestructive quantitative means to measure the conversion from monomer to polymer.
 
Publisher AMER CHEMICAL SOC
 
Date 2011-07-14T10:13:30Z
2011-12-26T12:48:20Z
2011-12-27T05:35:41Z
2011-07-14T10:13:30Z
2011-12-26T12:48:20Z
2011-12-27T05:35:41Z
1993
 
Type Article
 
Identifier MACROMOLECULES, 26(22), 5954-5958
0024-9297
http://dx.doi.org/10.1021/ma00074a017
http://dspace.library.iitb.ac.in/xmlui/handle/10054/3928
http://hdl.handle.net/10054/3928
 
Language en