Dielectric properties of A- and B-site doped BaTiO(3): Effect of La and Ga
DSpace at IIT Bombay
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Title |
Dielectric properties of A- and B-site doped BaTiO(3): Effect of La and Ga
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Creator |
GULWADE, D
GOPALAN, P |
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Subject |
barium-titanate ceramics
ferroelectric phase-transition relaxor ferroelectrics solid-solutions state pbtio3 origin ferroelectric properties diffuse phase transition doped batio(3) high temperature xrd |
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Description |
Extremely small amounts of La and Ga doping on the A- and B-site of BaTiO(3), respectively, resulting in a solid solution of the type Ba(1-3x)La(2x)Ti(1-3y)Ga(4y)O(3) have been investigated. The present work dwells on the influence of the individual dopants, namely La and Ga, on the dielectric properties of BaTiO(3). The compositions have been prepared by solid-state reaction. X-ray diffraction (XRD) reveals the presence of tetragonal (P4/mmm) phase. The XRD data has been analyzed using FULLPROF, a Rietveld refinement package. The microstructure have been studied by orientation imaging microscopy (OIM). The compositions have been characterized by dielectric spectroscopy between room temperature and 250 degrees C. Further, the nature of phase transition has been studied using high temperature XRD. The resulting Compounds exhibit high dielectric constant, enhanced diffuseness and low temperature coefficient of capacitance. (C) 2009
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Publisher |
ELSEVIER SCIENCE BV
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Date |
2011-07-24T18:00:31Z
2011-12-26T12:47:33Z 2011-12-27T05:36:12Z 2011-07-24T18:00:31Z 2011-12-26T12:47:33Z 2011-12-27T05:36:12Z 2009 |
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Type |
Article
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Identifier |
PHYSICA B-CONDENSED MATTER, 404(41609), 1799-1805
0921-4526 http://dx.doi.org/10.1016/j.physb.2009.02.026 http://dspace.library.iitb.ac.in/xmlui/handle/10054/6498 http://hdl.handle.net/10054/6498 |
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Language |
en
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