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Field-optimized initial state-based selective control of IBr photodissociation

DSpace at IIT Bombay

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Field Value
 
Title Field-optimized initial state-based selective control of IBr photodissociation
 
Creator BAIRAGI, DB
GROSS, P
MISHRA, MK
 
Subject coherent laser control
molecular-dynamics
chemical-reaction
quantum dynamics
bond breaking
excitation
evolution
systems
hcl
hod
 
Description A new scheme for controlling photodissociation through preparation of a variationally optimized linear superposition of field-free vibrational eigenstates is applied for selective control of IBr photodissociation. The dependence of IBr photodissociation on various field parameters and initial conditions is explored. In a broad range of field parameters, the product yield is shown to increase considerably when a photolysis pulse is applied to the variationally optimized linear combination as opposed to photolysis of IBr with the entire population in a single vibrational level. The frequency, intensity, and phase dependence of this enhancement is explored for both CW and Gaussian pulses.
 
Publisher AMER CHEMICAL SOC
 
Date 2011-07-14T04:03:35Z
2011-12-26T12:47:33Z
2011-12-27T05:36:20Z
2011-07-14T04:03:35Z
2011-12-26T12:47:33Z
2011-12-27T05:36:20Z
1997
 
Type Article
 
Identifier JOURNAL OF PHYSICAL CHEMISTRY A, 101(5), 759-763
1089-5639
http://dx.doi.org/10.1021/jp9615666
http://dspace.library.iitb.ac.in/xmlui/handle/10054/3855
http://hdl.handle.net/10054/3855
 
Language en