Field-optimized initial state-based selective control of IBr photodissociation
DSpace at IIT Bombay
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Title |
Field-optimized initial state-based selective control of IBr photodissociation
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Creator |
BAIRAGI, DB
GROSS, P MISHRA, MK |
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Subject |
coherent laser control
molecular-dynamics chemical-reaction quantum dynamics bond breaking excitation evolution systems hcl hod |
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Description |
A new scheme for controlling photodissociation through preparation of a variationally optimized linear superposition of field-free vibrational eigenstates is applied for selective control of IBr photodissociation. The dependence of IBr photodissociation on various field parameters and initial conditions is explored. In a broad range of field parameters, the product yield is shown to increase considerably when a photolysis pulse is applied to the variationally optimized linear combination as opposed to photolysis of IBr with the entire population in a single vibrational level. The frequency, intensity, and phase dependence of this enhancement is explored for both CW and Gaussian pulses.
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Publisher |
AMER CHEMICAL SOC
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Date |
2011-07-14T04:03:35Z
2011-12-26T12:47:33Z 2011-12-27T05:36:20Z 2011-07-14T04:03:35Z 2011-12-26T12:47:33Z 2011-12-27T05:36:20Z 1997 |
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Type |
Article
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Identifier |
JOURNAL OF PHYSICAL CHEMISTRY A, 101(5), 759-763
1089-5639 http://dx.doi.org/10.1021/jp9615666 http://dspace.library.iitb.ac.in/xmlui/handle/10054/3855 http://hdl.handle.net/10054/3855 |
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Language |
en
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