Cycloaddition of 6-hydroxy-2,6-dimethylcyclohexa-2,4-dienone: A stereoselective entry into functionalized bicyclo[2.2.2]octanes and a novel 1,2-migration of methyl group
DSpace at IIT Bombay
View Archive InfoField | Value | |
Title |
Cycloaddition of 6-hydroxy-2,6-dimethylcyclohexa-2,4-dienone: A stereoselective entry into functionalized bicyclo[2.2.2]octanes and a novel 1,2-migration of methyl group
|
|
Creator |
SINGH, V
CHANDRA, G MOBIN, SM |
|
Subject |
homoallyl radical rearrangement
1st total-synthesis enantioselective synthesis periodate oxidation route ring cyclohexa-2,4-dienones construction dimerization phenols cycloaddition cyclohexa-2,4-dienone diels-alder reaction bicyclo[2.2.2]octane 1,2-migration |
|
Description |
Cycloaddition of 6-hydroxy-2,6-dimethylcyclohexa-2,4-dienones with ethyl vinyl ether, butyl vinyl ether, vinyl acetate and vinyl phenyl sulphone leading to a stereoselective entry into bicyclo[2.2.2]octanes having quaternary methyl group is reported. A novel thermal 1,2-methyl migration has also been described.
|
|
Publisher |
COUNCIL SCIENTIFIC & INDUSTRIAL RES
|
|
Date |
2011-07-20T11:13:53Z
2011-12-26T12:51:27Z 2011-12-27T05:36:35Z 2011-07-20T11:13:53Z 2011-12-26T12:51:27Z 2011-12-27T05:36:35Z 2008 |
|
Type |
Article
|
|
Identifier |
INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 47(12), 1886-1891
0376-4699 http://dspace.library.iitb.ac.in/xmlui/handle/10054/5453 http://hdl.handle.net/10054/5453 |
|
Language |
en
|
|