FORCED-OSCILLATIONS OF CONCENTRATION IN TRANSPORT REACTORS
DSpace at IIT Bombay
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Title |
FORCED-OSCILLATIONS OF CONCENTRATION IN TRANSPORT REACTORS
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Creator |
PRASHANT, C
CHIDAMBARAM, M |
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Subject |
catalytic reactions
periodic operation model deactivation performance riser periodic operation forced oscillations concentration pulsing transport reactor catalyst deactivation |
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Description |
The performance of a transport catalytic reactor is analysed for an adsorption/desorption type model with Eley-Rideal surface kinetics with square wave oscillations in the feed concentration. The inlet average concentration of both the reactants over a period is assumed to be constant. Significant improvement in the yield of product is obtained by increasing the feed concentration of both the reactants in the first fraction of a period. The effect of adsorption capacity of the catalyst, reaction rate constants, and inlet feed mean concentration of the reactants are evaluated. The deactivation of active sites, due to product inhibition, introduces resonance in the yield versus cycle split. The yield of product shows a minimum with respect to cycle split for the type of forcing where one of the reactant concentrations increases and the second reactant concentration decreases in the first fraction of a period.
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Publisher |
CANADIAN SOC CHEMICAL ENGINEERING
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Date |
2011-07-19T12:03:37Z
2011-12-26T12:51:11Z 2011-12-27T05:37:41Z 2011-07-19T12:03:37Z 2011-12-26T12:51:11Z 2011-12-27T05:37:41Z 1990 |
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Type |
Article
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Identifier |
CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 68(6), 968-973
0008-4034 http://dspace.library.iitb.ac.in/xmlui/handle/10054/5292 http://hdl.handle.net/10054/5292 |
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Language |
en
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