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Novel layered copper phosphoramidate, which contains six-membered rings made of five different elements

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Title Novel layered copper phosphoramidate, which contains six-membered rings made of five different elements
 
Creator MURUGAVEL, R
SINGH, MP
 
Subject metal phosphonate chemistry
structural characterization
crystal-structures
complexes
transition
cobalt
wires
acid
 
Description Copper(II) perchlorate and (PhCONH)P(O)(OH)(2) (H(2)bpa) react in methanol to yield [Cu(Hbpa)(2)](n), a novel layered solid that displays several interesting features. Unlike the previously reported copper phosphonates, a rare hexacoordination around the metal is observed in the title compound because of the amide C=O coordination to Cu in addition to the phosphoramidate P-O coordination. The six-membered chelate rings present in the title compound are made up of five different elements (Cu, P, C, N, and O).
 
Publisher AMER CHEMICAL SOC
 
Date 2011-07-14T14:12:19Z
2011-12-26T12:48:25Z
2011-12-27T05:37:47Z
2011-07-14T14:12:19Z
2011-12-26T12:48:25Z
2011-12-27T05:37:47Z
2006
 
Type Article
 
Identifier INORGANIC CHEMISTRY, 45(23), 9154-9156
0020-1669
http://dx.doi.org/10.1021/ic061298i
http://dspace.library.iitb.ac.in/xmlui/handle/10054/3978
http://hdl.handle.net/10054/3978
 
Language en