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ELECTROCHEMICAL OXIDATION OF THIOCYANATE IN A 2-PHASE ELECTROLYTE

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Field Value
 
Title ELECTROCHEMICAL OXIDATION OF THIOCYANATE IN A 2-PHASE ELECTROLYTE
 
Creator KRISHNAN, P
GURJAR, VG
 
Subject ion
 
Description A two phase electrolysis method has been developed for preparation of thiocyanating reagent. The electrolyses were carried out using graphite electrodes using a two phase electrolytic medium made up of an aqueous solution of ammonium thiocyanate in 0.25 M H2SO4 and a nonaqueous solvent. The effect of experimental parameters, such as temperature and duration of electrolysis, nature of the nonaqueous solvent and volume fraction of the nonaqueous phase, on the process current efficiency were studied. The voltammetric studies in the nonaqueous phase established that trithiocyanate, (SCN)(3)(-1), was produced in the aqueous phase and was subsequently extracted into the nonaqueous phase.
 
Publisher CHAPMAN HALL LTD
 
Date 2011-07-19T15:38:34Z
2011-12-26T12:51:16Z
2011-12-27T05:37:50Z
2011-07-19T15:38:34Z
2011-12-26T12:51:16Z
2011-12-27T05:37:50Z
1995
 
Type Article
 
Identifier JOURNAL OF APPLIED ELECTROCHEMISTRY, 25(8), 792-796
0021-891X
http://dx.doi.org/10.1007/BF00648635
http://dspace.library.iitb.ac.in/xmlui/handle/10054/5346
http://hdl.handle.net/10054/5346
 
Language en