SECONDARY GRAIN-GROWTH IN AMMONIUM-NITRATE CRYSTALLIZATION
DSpace at IIT Bombay
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Title |
SECONDARY GRAIN-GROWTH IN AMMONIUM-NITRATE CRYSTALLIZATION
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Creator |
RAO, KVR
HARIHARAN, PL CHAKRABARTY, DK |
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Subject |
dendritic growth
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Description |
Crystallization and ageing of pure ammonium nitrate crystals was studied by scanning electron microscopy. Ageing the crystals beyond 1 h led to the growth of secondary grains along the grain boundaries of primary grains (140-200-mu-m). After 6 h ageing secondary growth along grain boundaries was not observed; instead, distinct clusters with morphologies similar to the secondary grains were formed. The ancillary growth obeys approximately the parabolic relation L = (Kt)1/n+1 where n = 1 justifies grain growth in the pure crystals, and its formation is ascribed to the dissolution of dendrites, edges and corners. The high interfacial activity and interparticle voids can affect the storage and mechanical properties of the material.
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Publisher |
CHAPMAN HALL LTD
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Date |
2011-07-20T06:16:02Z
2011-12-26T12:51:19Z 2011-12-27T05:37:56Z 2011-07-20T06:16:02Z 2011-12-26T12:51:19Z 2011-12-27T05:37:56Z 1991 |
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Type |
Article
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Identifier |
JOURNAL OF MATERIALS SCIENCE, 26(11), 3004-3008
0022-2461 http://dx.doi.org/10.1007/BF01124835 http://dspace.library.iitb.ac.in/xmlui/handle/10054/5377 http://hdl.handle.net/10054/5377 |
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Language |
en
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