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Structure of the phenylacetylene - Water complex as revealed by infrared-ultraviolet double resonance spectroscopy

DSpace at IIT Bombay

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Title Structure of the phenylacetylene - Water complex as revealed by infrared-ultraviolet double resonance spectroscopy
 
Creator SINGH, PC
BANDYOPADHYAY, B
PATWARI, GN
 
Subject vibrational spectroscopy
multiphoton ionization
stretching vibrations
matrix-isolation
supersonic jets
benzene
clusters
molecules
spectra
shifts
 
Description The structure of the phenylacetylene-water complex has been elucidated based on spectral shifts in electronic and vibrational transitions. Phenylacetylene forms a cyclic complex with water incorporating C-H center dot center dot center dot O and O-H center dot center dot center dot pi hydrogen bonds, which is different from both the benzene-water and acetylene-water complexes, even though phenylacetylene combines the features of both benzene and acetylene. Formation of such a complex can be rationalized on the basis of cooperativity between the two sets of hydrogen bonds.
 
Publisher AMER CHEMICAL SOC
 
Date 2011-07-14T22:38:04Z
2011-12-26T12:47:40Z
2011-12-27T05:38:04Z
2011-07-14T22:38:04Z
2011-12-26T12:47:40Z
2011-12-27T05:38:04Z
2008
 
Type Article
 
Identifier JOURNAL OF PHYSICAL CHEMISTRY A, 112(15), 3360-3363
1089-5639
http://dx.doi.org/10.1021/jp710311p
http://dspace.library.iitb.ac.in/xmlui/handle/10054/4086
http://hdl.handle.net/10054/4086
 
Language en