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pi(4s)+pi(2s) Cycloaddition of spiro[4,n]cyclic 1,3-dienes with quinones in homogeneous and aqueous micellar media: Synthesis of novel polycyclic cage diones

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Title pi(4s)+pi(2s) Cycloaddition of spiro[4,n]cyclic 1,3-dienes with quinones in homogeneous and aqueous micellar media: Synthesis of novel polycyclic cage diones
 
Creator SINGH, V
RAJU, RNS
 
Subject pentaprismane
 
Description Synthesis of novel cage polycyclic diones 22-27 via micellar Diels-Alder reaction of spirocyclopentadienes 7-9 with various quinones followed by intramolecular photocycioaddition has been reported. A simple phase transfer catalyzed preparation of the requisite dienes 7-9 has also been described. A remarkable micellar catalysis on the Diels-Alder reaction has been observed.
 
Publisher COUNCIL SCIENTIFIC INDUSTRIAL RESEARCH
 
Date 2011-07-20T21:41:55Z
2011-12-26T12:51:42Z
2011-12-27T05:38:10Z
2011-07-20T21:41:55Z
2011-12-26T12:51:42Z
2011-12-27T05:38:10Z
1996
 
Type Article
 
Identifier INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 35(4), 303-311
0376-4699
http://dspace.library.iitb.ac.in/xmlui/handle/10054/5661
http://hdl.handle.net/10054/5661
 
Language en