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A novel dimeric copper salicylate with an undissociated COOH group: Synthesis and crystal structure of [Cu-2(HSal)(Sal)(2,2 '-bpy)(2)](ClO4)

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Title A novel dimeric copper salicylate with an undissociated COOH group: Synthesis and crystal structure of [Cu-2(HSal)(Sal)(2,2 '-bpy)(2)](ClO4)
 
Creator PALANISAMI, N
PRABUSANKAR, G
MURUGAVEL, R
 
Subject earth metal-ions
coordination polymers
complexes
acid
perchlorate
1,10-phenanthroline
architectures
dihydrate
ligands
copper salicylate
hydrogen bonding
crystal structure
 
Description A dinuclear copper salicylate [Cu-2(HSal)(Sal)(2,2'-bpy)(2)](ClO4) (1) (H(2)Sal = salicylic acid) has been synthesized and characterized with the aid of elemental analysis and infrared, ultraviolet and fluorescence spectroscopic studies. The molecular structure of 1, determined by single-crystal X-ray diffraction studies, shows the presence of incompletely deprotonated salicylate ligands in the complex. Hydrogen bonding interactions and pi-pi aromatic stacking lead to the formation of 2D polymeric structure in the solid state. (C) 2006
 
Publisher ELSEVIER SCIENCE BV
 
Date 2011-07-22T19:26:31Z
2011-12-26T12:52:32Z
2011-12-27T05:38:35Z
2011-07-22T19:26:31Z
2011-12-26T12:52:32Z
2011-12-27T05:38:35Z
2006
 
Type Article
 
Identifier INORGANIC CHEMISTRY COMMUNICATIONS, 9(10), 1002-1006
1387-7003
http://dx.doi.org/10.1016/j.inoche.2006.05.025
http://dspace.library.iitb.ac.in/xmlui/handle/10054/6333
http://hdl.handle.net/10054/6333
 
Language en