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Fluid chemistry and depositional mechanism of the epigenetic, discordant ores of the Proterozoic, carbonate-hosted, Zawarmala Pb-Zn deposit, Udaipur district, India

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Title Fluid chemistry and depositional mechanism of the epigenetic, discordant ores of the Proterozoic, carbonate-hosted, Zawarmala Pb-Zn deposit, Udaipur district, India
 
Creator TALLURI, JK
PANDALAI, HS
JADHAV, GN
 
Subject multicomponent chemical-equilibria
northwestern india
rajasthan
remobilization
equation
minerals
system
phase
rocks
gases
 
Description The Proterozoic, carbonate-hosted, Zawarmala Pb-Zn deposit has stratiform, banded pyrite-sphalerite ore, as well as discordant, sphalerite-galena veins and rich massive galena ore shoots. The mechanisms of deposition of discordant vein and massive ores have been studied using speciation and solubility calculations based on ore fluid characteristics and physical parameters inferred from petrography, fluid inclusion studies, and leachate analysis. Massive galena ore, which is the economic ore type, cuts across the earlier, F-2-related, vein-type ore and is distinct from the vein-type ore in terms of mineralogy, texture, and fluid inclusion characteristics. Fluid inclusions in quartz associated with the ores show that fluids forming vein-type ore are low-salinity (4.3-14.7 wt % NaCl equiv) H2O-NaCl fluids. The trapping temperature of vein-type ore fluid was estimated to be in the range of 395 degrees to 290 degreesC at a pressure of about 1,450 bars. Fluids associated with massive galena ore are H2O-CO2-NaCl fluids of lower salinity (about 3-4 wt % NaCl equiv). The wide variation in X-CO2 of fluid inclusions that occur in close proximity to each other within the same sample of massive ore suggests heterogeneous entrapment of the low-salinity H2O-CO2-NaCl fluids. From the intersection of isochores of local, homogeneously entrapped CO2 and aqueous biphase fluids of unmixed CO2-H2O-NaCl fluid, trapping temperature fluid was estimated to be between 250 degrees and 150 degreesC at pressures of 2,000 to 750 bars. Despite the low salinity of the ore fluids, speciation studies show that chloride complexes are dominant over most of the temperature range of interest in both ore fluids. The only bisulfide complex of importance is Pb(HS)(2)(0) which is dominant below 175 degreesC in fluids associated with massive galena ore. Data from fluid inclusions and solubility calculations reveal that cooling is the important mechanism of vein-type ore deposition. In contrast, physicochemical data indicate that an increase in reduced sulfur, by mixing a regional, high metal content, low sulfur fluid with a local, high sulfur fluid at the site of deposition, was the mechanism for massive galena ore deposition. The difference in oxidation state (and therefore also in metal content) of the two fluids is inferred to be a significant factor that caused differences in the modes of deposition of the two ore types and the relatively high value of X-CO2 (0.2033) in fluids associated with massive galena ore.
 
Publisher ECONOMIC GEOLOGY PUBL CO
 
Date 2011-07-21T12:24:29Z
2011-12-26T12:52:00Z
2011-12-27T05:38:53Z
2011-07-21T12:24:29Z
2011-12-26T12:52:00Z
2011-12-27T05:38:53Z
2000
 
Type Article
 
Identifier ECONOMIC GEOLOGY AND THE BULLETIN OF THE SOCIETY OF ECONOMIC GEOLOGISTS, 95(7), 1505-1525
0361-0128
http://dx.doi.org/10.2113/95.7.1505
http://dspace.library.iitb.ac.in/xmlui/handle/10054/5865
http://hdl.handle.net/10054/5865
 
Language en