Record Details

ACETYLENIC DERIVATIVES OF FE-2(CO)(6)(MU-SE-2) - SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF [(CO)(6)FE-2(MU-SEC(H)=C(H)SE)] AND [((CO)(6)FE2SE2)(2)(MU-C(H)-C(H))]

DSpace at IIT Bombay

View Archive Info
 
 
Field Value
 
Title ACETYLENIC DERIVATIVES OF FE-2(CO)(6)(MU-SE-2) - SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF [(CO)(6)FE-2(MU-SEC(H)=C(H)SE)] AND [((CO)(6)FE2SE2)(2)(MU-C(H)-C(H))]
 
Creator MATHUR, P
DASH, AK
HOSSAIN, MM
SATYANARAYANA, CVV
 
Subject bond reduction
clusters
complexes
ligands
fe2(co)6(mu-se2)
se
te
iron
selenium
 
Description The new acetylenic derivatives [(CO)(6)Fe-2{mu-SeC(H)=C(H)Se}] and [{(CO)(6)Fe2Se2}(2){mu-C(H)-C(H)}] have been isolated from the room-temperature reaction of Fe-2(CO)(6)(mu-Se-2) with acetylene in methanol solvent containing sodium acetate. The products have been characterized by IR and H-1, C-13 and Se-77 NMR spectroscopy. The NMR spectroscopic features of the related phenylacetylene derivatives[(CO)(6)Fe-2{mu-SeC(Ph)=C(H)Se}] and [{(CO)(6)Fe2Se2}(2){mu-C(Ph)-C(H)}] are also reported.
 
Publisher ELSEVIER SCIENCE SA LAUSANNE
 
Date 2011-07-29T03:10:06Z
2011-12-26T12:47:43Z
2011-12-27T05:38:57Z
2011-07-29T03:10:06Z
2011-12-26T12:47:43Z
2011-12-27T05:38:57Z
1995
 
Type Article
 
Identifier JOURNAL OF ORGANOMETALLIC CHEMISTRY, 493(1-2), 257-260
0022-328X
http://dx.doi.org/10.1016/0022-328X(94)05350-K
http://dspace.library.iitb.ac.in/xmlui/handle/10054/7562
http://hdl.handle.net/10054/7562
 
Language en