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ADDITION OF METHYLENE GROUPS TO FE3(CO)9(MU-3-TE)2

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Title ADDITION OF METHYLENE GROUPS TO FE3(CO)9(MU-3-TE)2
 
Creator MATHUR, P
REDDY, VD
BOHRA, R
 
Subject polynuclear metal-complexes
x-ray structure
crystal-structures
molecular-structure
bridging carbene
carbyne ligands
multiple bonds
mu-methylene
chemistry
iron
 
Description At room temperature, Fe3(CO)9(mu-Te)2 reacts with diazomethane to form (CO)6Fe2(mu-TeCH2Te) (I) and (CO)6Fe2Te2(CH2)2 (II). Complexes I and II have been separated by chromatography and characterised by IR and NMR spectroscopy, mass spectrometry and microanalysis. Complex I was also subjected to an X-ray diffraction study. The crystals are monoclinic, space group P2(1)/c with a = 6.864(2), b = 13.926(3), c = 14.159(3) angstrom, beta = 104.43(2)-degrees, V = 1310.6(5) angstrom, Z = 4, D(c) = 2.79 g cm-3 and R = 0.043.
 
Publisher ELSEVIER SCIENCE SA LAUSANNE
 
Date 2011-07-29T03:14:18Z
2011-12-26T12:47:43Z
2011-12-27T05:38:58Z
2011-07-29T03:14:18Z
2011-12-26T12:47:43Z
2011-12-27T05:38:58Z
1991
 
Type Article
 
Identifier JOURNAL OF ORGANOMETALLIC CHEMISTRY, 401(3), 339-346
0022-328X
http://dx.doi.org/10.1016/0022-328X(91)86230-N
http://dspace.library.iitb.ac.in/xmlui/handle/10054/7563
http://hdl.handle.net/10054/7563
 
Language en