Correlation between sorbent characteristics and metal sorption capacity of soils around Mumbai: Implications on environmental hazard management
DSpace at IIT Bombay
View Archive InfoField | Value | |
Title |
Correlation between sorbent characteristics and metal sorption capacity of soils around Mumbai: Implications on environmental hazard management
|
|
Creator |
MOULIK, MR
BANERJEE, S MUKHERJI, S |
|
Subject |
island city
sediments india pollution bombay metal sorption soils geosorbents isotherm models mumbai |
|
Description |
The present study involves the characterization of soils on the basis of physical and chemical properties including grain size, surface area, cation exchange capacity (CEC), organic matter, types of clay minerals and point of zero charge, which make them effective as geosorbents and correlation of these sorbent characteristics to their metal sorption capacity. The study on characterization of soils involved four types of soils from a single soil profile, a black cotton soil and a brick making soil collected from Mumbai and its surroundings. Completely mixed batch reactor systems were utilized to obtain isotherms for nickel and cadmium sorption on three geosorbents, i.e. top-most profile soil, bottom-most profile soil and black cotton soil. The experimental protocol consisted of geosorbent characterization, kinetic study of nickel and cadmium sorption to determine the equilibrium time and sorption equilibrium studies. The sorption results indicate that CEC, presence of expandable clay minerals and point of zero charge have significant effect on metal sorption. It is also observed that sorbate specific properties such as ionic charge, ionic radius, electronegativity, etc also affect the extent of sorption.
|
|
Publisher |
GEOLOGICAL SOC INDIA
|
|
Date |
2011-07-29T22:01:07Z
2011-12-26T12:52:39Z 2011-12-27T05:39:17Z 2011-07-29T22:01:07Z 2011-12-26T12:52:39Z 2011-12-27T05:39:17Z 2005 |
|
Type |
Article
|
|
Identifier |
JOURNAL OF THE GEOLOGICAL SOCIETY OF INDIA, 66(4), 445-452
0016-7622 http://dspace.library.iitb.ac.in/xmlui/handle/10054/7846 http://hdl.handle.net/10054/7846 |
|
Language |
en
|
|