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CARBON-SELENIUM BOND-CLEAVAGE IN THE DOUBLE BUTTERFLY COMPLEX [((CO)6FE2(MU-SE)2)2(C(PH)-C(H))] AND THE SYNTHESIS AND X-RAY STRUCTURAL-ANALYSIS OF ITS DPPE-SUBSTITUTED DERIVATIVE
DSpace at IIT Bombay
View Archive Info| Field | Value | |
| Title |
CARBON-SELENIUM BOND-CLEAVAGE IN THE DOUBLE BUTTERFLY COMPLEX [((CO)6FE2(MU-SE)2)2(C(PH)-C(H))] AND THE SYNTHESIS AND X-RAY STRUCTURAL-ANALYSIS OF ITS DPPE-SUBSTITUTED DERIVATIVE
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| Creator |
MATHUR, P
HOSSAIN, MM MAHON, MF |
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| Subject |
alkynes
ligands fe2(co)6(mu-se2) reactivity reduction iron selenium x-ray diffraction |
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| Description |
At room temperature, the double butterfly complex [{(CO)6Fe2(mu-Se)2}2(C(Ph)-C(H)] reacted with Pt(C2H4)(PPh3)2 to give [(CO)6Fe2(mu-SeC(Ph)C(H)Se)], [(CO)6Fe2Pt(PPh3)2(mu-SeC(Ph)C(H)Se}] and [(CO)6Fe2(mu3-Se)2Pt(PPh3)2]. It reacted with dppe to form the substituted derivative [{(CO)5Fe2(mu-Se)2}2C(Ph)C(H)(mu-dppe)], which was subjected to an X-ray diffraction analysis. The crystal of [{(CO)5Fe2(mu-Se)2}2C(Ph)C(H)(mu-dppe)] is triclinic with the space group P1BAR, a = 12.969(1), b = 13.032(1), c = 18.669(1) angstrom, alpha = 76.81(1), beta = 72.74(1), gamma = 63.99(1)degrees, Z = 2. The structure was refined by the block-matrix least squares method. The final R and R(w) values were 0.0435 and 0.0492 respectively.
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| Publisher |
ELSEVIER SCIENCE SA LAUSANNE
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| Date |
2011-07-29T04:04:54Z
2011-12-26T12:47:45Z 2011-12-27T05:39:32Z 2011-07-29T04:04:54Z 2011-12-26T12:47:45Z 2011-12-27T05:39:32Z 1994 |
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| Type |
Article
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| Identifier |
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 471(1-2), 185-191
0022-328X http://dx.doi.org/10.1016/0022-328X(94)88124-3 http://dspace.library.iitb.ac.in/xmlui/handle/10054/7580 http://hdl.handle.net/10054/7580 |
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| Language |
en
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