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Cope-house cyclization strategy for the synthesis of pyrrolizidines: An expedient route to 5-epi-hyacinthacine A(3) and 5-epi-hyacinthacine A(5)

DSpace at IIT Bombay

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Title Cope-house cyclization strategy for the synthesis of pyrrolizidines: An expedient route to 5-epi-hyacinthacine A(3) and 5-epi-hyacinthacine A(5)
 
Creator KALIAPPAN, KP
DAS, P
 
Subject pyrrolidine-n-oxides
unsaturated hydroxylamines
glycosidase inhibitors
elimination-reactions
natural occurrence
cyclic nitrones
(+)-australine
alkaloids
ym-181741
product
nitrone
grignard reaction
cope-house cyclization
hydrogenation
hyacinthacine
 
Description An expedient Cope-House cyclization strategy is reported here for the synthesis of several polyhydroxy pyrrolizidine alkaloids starting from sugar-derived nitrones.
 
Publisher GEORG THIEME VERLAG KG
 
Date 2011-07-30T08:20:41Z
2011-12-26T12:52:44Z
2011-12-27T05:39:36Z
2011-07-30T08:20:41Z
2011-12-26T12:52:44Z
2011-12-27T05:39:36Z
2008
 
Type Article
 
Identifier SYNLETT, (6), 841-844
0936-5214
http://dx.doi.org/10.1055/s-2008-1042898
http://dspace.library.iitb.ac.in/xmlui/handle/10054/7900
http://hdl.handle.net/10054/7900
 
Language en