Record Details

Molecular complexity from aromatics - An efficient route to 1,8-dimethyl-5-spirocyclopropanetricyclo[6.3.0.0(2,6)]undec-10-one: A potential intermediate for synthesis of ceratopicanol

DSpace at IIT Bombay

View Archive Info
 
 
Field Value
 
Title Molecular complexity from aromatics - An efficient route to 1,8-dimethyl-5-spirocyclopropanetricyclo[6.3.0.0(2,6)]undec-10-one: A potential intermediate for synthesis of ceratopicanol
 
Creator SINGH, V
CHANDRA, G
MOBIN, SM
 
Subject 1st total-synthesis
linear triquinane
cyclization reactions
holosynthon concept
acid
(+/-)-ceratopicanol
sesquiterpenoids
(+/-)-hirsutene
rearrangement
hypnophilin
cycloaddition
oxa-di-pi-methane rearrangement
triquinanes
diels-alder reaction
 
Description A new stereoselective synthesis of linearly fused triquinane intermediate from a simple aromatic precursor is described. Cycloaddition of cycloliexa-2.4-dienone and photochemical oxa-di-pi-methane rearrangement in a functionalized tricycloundecenone are the key features of our methodology.
 
Publisher GEORG THIEME VERLAG KG
 
Date 2011-07-30T08:36:08Z
2011-12-26T12:52:45Z
2011-12-27T05:39:37Z
2011-07-30T08:36:08Z
2011-12-26T12:52:45Z
2011-12-27T05:39:37Z
2008
 
Type Article
 
Identifier SYNLETT, (15), 2267-2270
0936-5214
http://dx.doi.org/10.1055/s-2008-1078592
http://dspace.library.iitb.ac.in/xmlui/handle/10054/7904
http://hdl.handle.net/10054/7904
 
Language en