Record Details

Designed construction of mixed-metal, mixed chalcogenide clusters

DSpace at IIT Bombay

View Archive Info
 
 
Field Value
 
Title Designed construction of mixed-metal, mixed chalcogenide clusters
 
Creator MATHUR, P
 
Subject cluster
chalcogen
mixed-metal
 
Description Room temperature reactions between Fe-2(CO)(6)(mu -EE'), (E and E' = S, Se or Te) and M(CO)(5)(thf), M = Cr, Mo or W yield three types of clusters, the formation of each type clearly dependent on the nature of E and E' present in Fe-2(CO)(6)(mu -EE') and on the nature of M in M(CO)(5)(thf). While the Mo and W adducts are based on square pyramidal heavy atom cores, the Cr adduct has an unusual structure and can be considered as an inorganic analog of quadricyclane.
 
Publisher GORDON BREACH PUBLISHING, TAYLOR & FRANCIS GROUP
 
Date 2011-07-30T09:33:45Z
2011-12-26T12:52:46Z
2011-12-27T05:39:39Z
2011-07-30T09:33:45Z
2011-12-26T12:52:46Z
2011-12-27T05:39:39Z
1998
 
Type Article
 
Identifier PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 136(), 535-540
1042-6507
http://dx.doi.org/10.1080/10426509808042658
http://dspace.library.iitb.ac.in/xmlui/handle/10054/7920
http://hdl.handle.net/10054/7920
 
Language en