COPOLYMERIZATION OF ALKYL ALPHA-CHLOROACRYLATES WITH METHYL-METHACRYLATE
DSpace at IIT Bombay
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Title |
COPOLYMERIZATION OF ALKYL ALPHA-CHLOROACRYLATES WITH METHYL-METHACRYLATE
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Creator |
PATHAK, CP
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Subject |
resist polymers
radiolysis |
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Description |
Hexyl alpha-chloroacrylate (HCA) and cyclohexyl alpha-chloroacrylate (CCA) have been copolymerized with methyl methacrylate (MMA) in toluene at 55-degrees-C using azobisiso-butyronitrile (AIBN) as initiator. Copolymer compositions have been determined both by H-1 NMR and elemental analyses. For copolymerization of MMA (M1) with HCA (M2), the reactivity ratios (RR) are r1 = 0.47 +/- 0.19 and r2 = 0.81 +/- 0.51 and with CCA the values are r1 = 0.76 +/- 0.31 and r2 = 2.30 +/- 1.73. Thermal properties of these copolymers have also been investigated.
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Publisher |
HUTHIG & WEPF VERLAG
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Date |
2011-07-31T07:37:52Z
2011-12-26T12:52:53Z 2011-12-27T05:39:51Z 2011-07-31T07:37:52Z 2011-12-26T12:52:53Z 2011-12-27T05:39:51Z 1991 |
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Type |
Article
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Identifier |
ANGEWANDTE MAKROMOLEKULARE CHEMIE, 184(), 147-155
0003-3146 http://dx.doi.org/10.1002/apmc.1991.051840113 http://dspace.library.iitb.ac.in/xmlui/handle/10054/8032 http://hdl.handle.net/10054/8032 |
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Language |
en
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