COPOLYMERIZATION OF TRI-NORMAL-BUTYLTIN-ALPHA-CHLOROACRYLATE WITH 2-HYDROXYALKYL METHACRYLATES
DSpace at IIT Bombay
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Title |
COPOLYMERIZATION OF TRI-NORMAL-BUTYLTIN-ALPHA-CHLOROACRYLATE WITH 2-HYDROXYALKYL METHACRYLATES
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Creator |
JOSHI, RR
GUPTA, SK DHARIA, JR |
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Description |
Copolymers of tri-n-butyltin-alpha-chloracrylate (TCA) with 2-hydroxyethyl methacrylate (HEMA) and 2-hydroxypropyl methacrylate (HPMA) were synthesized in solution at 55-degrees-C using azobisisobutyronitrile as initiator. Copolymer compositions were determined by tin analysis. Monomer reactivity ratios were calculated by the Kelen-Tudos method. The copolymers were further characterized by IR, H-1-NMR, TGA, DSC, XRD and solubility. Biotoxicity studies of the copolymers are also reported. The copolymer system is compared with similar copolymers of tri-n-butyltin methacrylate.
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Publisher |
HUTHIG & WEPF VERLAG
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Date |
2011-07-31T07:42:04Z
2011-12-26T12:52:53Z 2011-12-27T05:39:51Z 2011-07-31T07:42:04Z 2011-12-26T12:52:53Z 2011-12-27T05:39:51Z 1991 |
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Type |
Article
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Identifier |
ANGEWANDTE MAKROMOLEKULARE CHEMIE, 189(), 1-11
0003-3146 http://dx.doi.org/10.1002/apmc.1991.051890101 http://dspace.library.iitb.ac.in/xmlui/handle/10054/8033 http://hdl.handle.net/10054/8033 |
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Language |
en
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