Record Details

Suzuki-Miyaura, Mizoroki-Heck carbon carbon coupling and hydrogenation reactions catalysed by Pd(II) and Rh(I) complexes containing cyclodiphosphazane cis-{(t)BuNP(OC(6)H(4)OMe-o)}(2)

DSpace at IIT Bombay

View Archive Info
 
 
Field Value
 
Title Suzuki-Miyaura, Mizoroki-Heck carbon carbon coupling and hydrogenation reactions catalysed by Pd(II) and Rh(I) complexes containing cyclodiphosphazane cis-{(t)BuNP(OC(6)H(4)OMe-o)}(2)
 
Creator MOHANTY, S
BALAKRISHNA, MS
 
Subject metal-complexes
aryl bromides
copper(i) coordination
reversible conversion
ligands
phosphinite
chemistry
ruthenium(ii)
chlorides
bearing
cyclodiphosphazane
catalysis
palladium and rhodium complexes
suzuki miyaura reactions
mizoroki heck reactions
hydrogenation reactions
 
Description The catalytic activity of the palladium complex cis-[PdCl(2)f((t)BuNP(OC(6)H(4)OMe-o))(2)-KP}(2)] (2) containing cis-{(t)BuNP(OC(6)H(4)OMe-o)}(2) (1) in Suzuki Miyaura and Mizoroki Heck carbon carbon cross coupling reactions is described. The compound 2 also displays very high activity in Mizoroki Heck coupling reactions. The rhodium(I) complex [RhCl(COD)(((t)BuNP(OC(6)H(4)OMe-o))(2)-kappa P] (3) acts as an excellent catalyst for the hydrogenation of several terminal olefins.
 
Publisher INDIAN ACAD SCIENCES
 
Date 2011-08-01T23:17:56Z
2011-12-26T12:53:32Z
2011-12-27T05:39:54Z
2011-08-01T23:17:56Z
2011-12-26T12:53:32Z
2011-12-27T05:39:54Z
2010
 
Type Article
 
Identifier JOURNAL OF CHEMICAL SCIENCES, 122(2), 137-142
0253-4134
http://dspace.library.iitb.ac.in/xmlui/handle/10054/8573
http://hdl.handle.net/10054/8573
 
Language en