Record Details

TRANSITION-METAL SACCHARIDE INTERACTIONS - SYNTHESIS AND CHARACTERIZATION OF VANADYL SACCHARIDES

DSpace at IIT Bombay

View Archive Info
 
 
Field Value
 
Title TRANSITION-METAL SACCHARIDE INTERACTIONS - SYNTHESIS AND CHARACTERIZATION OF VANADYL SACCHARIDES
 
Creator SREEDHARA, A
RAGHAVAN, MSS
RAO, CP
 
Subject blood-cells
d-fructose
d-glucose
complexes
vanadium(iv)
chemistry
alkoxides
oxidation
chromate
binding
 
Description Low molecular weight saccharide complexes of vanadium of the type [VO(sacch)(2)](2-), were synthesized for the first time by simple and reproducible methods in nonaqueous media. These reactions yielded water-soluble products which were characterized by various analytical and spectroscopic techniques and by cyclic voltammetry. The vanadyl D-glucose complex 1 shows a resemblance to a natural vanadium-binding component vanadobin, isolated from the tunicate Ascidia sydneiensis samea. All the saccharide complexes are stable in solution for long periods under ambient conditions without being oxidised and showed no hydrolysis in the pH range 2-12. All the saccharide complexes reported in this paper show evidence for the V(IV) species.
 
Publisher ELSEVIER SCIENCE BV
 
Date 2011-07-27T04:23:05Z
2011-12-26T12:53:34Z
2011-12-27T05:40:02Z
2011-07-27T04:23:05Z
2011-12-26T12:53:34Z
2011-12-27T05:40:02Z
1994
 
Type Article
 
Identifier CARBOHYDRATE RESEARCH, 264(2), 227-235
0008-6215
http://dx.doi.org/10.1016/S0008-6215(05)80008-4
http://dspace.library.iitb.ac.in/xmlui/handle/10054/7113
http://hdl.handle.net/10054/7113
 
Language en