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Catalytic oxidation of alkylaromatics over mesoporous (Cr)MCM-41

DSpace at IIT Bombay

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Title Catalytic oxidation of alkylaromatics over mesoporous (Cr)MCM-41
 
Creator SAKTHIVEL, A
BADAMALI, SK
SELVAM, P
 
Subject diffuse-reflectance spectroscopy
molecular-sieves
selective oxidation
liquid-phase
chromium
alcohols
mcm-41
silica
tbhp
(cr)mcm-41
alkylaromatics
catalytic oxidation
mesoporous materials
 
Description Liquid-phase catalytic oxidation of certain alkylaromatics over mesoporous (Cr)MCM-41 molecular sieves in the presence of chlorobenzene and tertiary butylhydroperoxide showed high substrate conversion and excellent product selectivity. The high catalytic activity of the materials is attributed to the complete oxidation of chromium ions to hexavalent chromium and the absence of pentavalent chromium in the mesoporous matrix.
 
Publisher KLUWER ACADEMIC/PLENUM PUBL
 
Date 2011-08-17T09:26:23Z
2011-12-26T12:55:28Z
2011-12-27T05:40:39Z
2011-08-17T09:26:23Z
2011-12-26T12:55:28Z
2011-12-27T05:40:39Z
2002
 
Type Article
 
Identifier CATALYSIS LETTERS, 80(1-2), 73-76
1011-372X
http://dx.doi.org/10.1023/A:1015330827806
http://dspace.library.iitb.ac.in/xmlui/handle/10054/9825
http://hdl.handle.net/10054/9825
 
Language en