Synthesis of CaTiO3 from calcium titanyl oxalate hexahydrate (CTO) as precursor employing microwave heating technique
DSpace at IIT Bombay
View Archive InfoField | Value | |
Title |
Synthesis of CaTiO3 from calcium titanyl oxalate hexahydrate (CTO) as precursor employing microwave heating technique
|
|
Creator |
PATIL, BM
SRINIVASA, RS DHARWADKAR, SR |
|
Subject |
mechanochemical synthesis
dielectric-properties temperature ceramics immobilization mixture powder ceramics synroc perovskites electronic materials microwave synthesis catio3 |
|
Description |
Calcium titanate, CaTiO3, an important microwave dielectric material and one of major phases in synroc (synthetic rock), a titanate ceramic with potential application for fixation of high level nuclear waste was synthesized from calcium titanyl oxalate [CaTiO (C2O4)(2)-6H(2)O] (CTO) by employing microwave heating technique. CTO heated in microwave heating system in air at 500 degrees C for 1 h gave a perovskite, CaTiO3. The product obtained by heating of CTO in the same system at 700 degrees C for the same duration was however, much more crystalline. CaTiO3 obtained by the present method was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and BET surface area measurement.
|
|
Publisher |
INDIAN ACADEMY SCIENCES
|
|
Date |
2011-08-02T08:27:21Z
2011-12-26T12:53:47Z 2011-12-27T05:40:49Z 2011-08-02T08:27:21Z 2011-12-26T12:53:47Z 2011-12-27T05:40:49Z 2007 |
|
Type |
Article
|
|
Identifier |
BULLETIN OF MATERIALS SCIENCE, 30(3), 225-229
0250-4707 http://dx.doi.org/10.1007/s12034-007-0040-7 http://dspace.library.iitb.ac.in/xmlui/handle/10054/8725 http://hdl.handle.net/10054/8725 |
|
Language |
en
|
|