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TRANSITION-METAL SACCHARIDE CHEMISTRY - SYNTHESIS AND CHARACTERIZATION OF SOME MONOSACCHARIDE COMPLEXES

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Title TRANSITION-METAL SACCHARIDE CHEMISTRY - SYNTHESIS AND CHARACTERIZATION OF SOME MONOSACCHARIDE COMPLEXES
 
Creator KAIWAR, SP
BANDWAR, RP
RAGHAVAN, MSS
RAO, CP
 
Subject d-glucose
structural characterization
potassium chromate
ion binding
d-fructose
sugar
adducts
reduction
1st row transition metal saccharide complexes
syntheses and characterization
absorption, ir, nmr, epr spectroscopies
magnetic and electrochemical studies
cr(iii)-induced dna cleavage
 
Description Synthesis and characterization of mononuclear complexes of Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) with D-fructose and dinuclear complexes of Cr(III) with D-glucose, D-fructose, and L-sorbose are reported. Cyclic voltammetric studies of these complexes suggest their robustness over a wide pH range. Cr(III)-saccharide complexes are found to affect the structure of pSV2 neo DNA irreversibly.
 
Publisher INDIAN ACADEMY SCIENCES
 
Date 2011-08-02T09:19:21Z
2011-12-26T12:53:48Z
2011-12-27T05:40:51Z
2011-08-02T09:19:21Z
2011-12-26T12:53:48Z
2011-12-27T05:40:51Z
1994
 
Type Article
 
Identifier PROCEEDINGS OF THE INDIAN ACADEMY OF SCIENCES-CHEMICAL SCIENCES, 106(3), 743-752
0253-4134
http://dspace.library.iitb.ac.in/xmlui/handle/10054/8741
http://hdl.handle.net/10054/8741
 
Language en