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A double helix is the repeating unit in a luminescent calcium 5-aminoisophthalate supramolecular edifice with water-filled hexagonal channels

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Title A double helix is the repeating unit in a luminescent calcium 5-aminoisophthalate supramolecular edifice with water-filled hexagonal channels
 
Creator MURUGAVEL, R
KUMAR, P
WALAWALKAR, MG
MATHIALAGAN, R
 
Subject ray crystal-structures
earth metal-ions
coordination polymer
hydrothermal synthesis
aminobenzoic acids
center-dot
complexes
molecules
design
chemistry
 
Description Calcium 5-aminoisophthalate {[Ca(AlP)(OH2)(4)](H2O)}infinity (1), synthesized from Ca(OH)2 and HAP, exists as a double helix. Hydrogen-bonding interactions between metal-bound water molecules, carboxylate oxygen, and the -NH2 group result in the formation of a supramolecular assembly, where the double helices are connected to each other to form hexagonal channels filled with water molecules.
 
Publisher AMER CHEMICAL SOC
 
Date 2011-07-13T13:29:45Z
2011-12-26T12:47:53Z
2011-12-27T05:41:32Z
2011-07-13T13:29:45Z
2011-12-26T12:47:53Z
2011-12-27T05:41:32Z
2007
 
Type Article
 
Identifier INORGANIC CHEMISTRY, 46(17), 6828-6830
0020-1669
http://dx.doi.org/10.1021/ic070113k
http://dspace.library.iitb.ac.in/xmlui/handle/10054/3683
http://hdl.handle.net/10054/3683
 
Language en