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Catalytic hydrodehalogenation of aryl halides, reduction of nitroarenes and reductive cleavage of azo compounds over mesoporous PdMCM-41 molecular sieves under transfer hydrogenation conditions

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Title Catalytic hydrodehalogenation of aryl halides, reduction of nitroarenes and reductive cleavage of azo compounds over mesoporous PdMCM-41 molecular sieves under transfer hydrogenation conditions
 
Creator SELVAM, P
MOHAPATRA, SK
SONAVANE, SU
JAYARAM, R
 
Subject chlorinated hydrocarbons
heterogeneous catalysts
selective oxidation
carbonyl-compounds
room-temperature
organic halides
aromatic nitro
dehalogenation
aluminophosphates
efficient
aryl halides
nitroarenes
azo compounds
catalytic transfer hydrogenation
pdmcm-41
mesoporous molecular sieves
 
Description A novel, efficient and eco-friendly PdMCM-41 catalyst is put forward for the hydrodehalogenation of aryl halides, reduction of nitroarenes and reductive cleavage of azo compounds by catalytic transfer hydrogenation (CTH) method. The results indicate that the transformations occur in elegant and rapid manner with excellent yields. Furthermore, the catalyst can easily be recovered and reused without practically affecting the yields for up to three cycles. (C) 2003
 
Publisher ELSEVIER SCIENCE BV
 
Date 2011-07-24T12:16:10Z
2011-12-26T12:54:23Z
2011-12-27T05:42:14Z
2011-07-24T12:16:10Z
2011-12-26T12:54:23Z
2011-12-27T05:42:14Z
2004
 
Type Article
 
Identifier APPLIED CATALYSIS B-ENVIRONMENTAL, 49(4), 251-255
0926-3373
http://dx.doi.org/10.1016/j.apcatb.2003.12.013
http://dspace.library.iitb.ac.in/xmlui/handle/10054/6420
http://hdl.handle.net/10054/6420
 
Language en