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CHROMATE REDUCTION - REDUCTION OF POTASSIUM CHROMATE BY D-GLUCOSE AND D-FRUCTOSE TO FORM CR(III)-SACCHARIDE COMPLEXES

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Title CHROMATE REDUCTION - REDUCTION OF POTASSIUM CHROMATE BY D-GLUCOSE AND D-FRUCTOSE TO FORM CR(III)-SACCHARIDE COMPLEXES
 
Creator RAO, CP
KAIWAR, SP
 
Subject electron-paramagnetic-res
chromium(vi)
glutathione
mechanism
adducts
cr(vi)
sugar
cr3+
ion
 
Description The reduction of chromate by saccharides is of paramount importance in the context of chromium transport in biological and ecological systems. Potassium chromate has been shown to be reduced by D-glucose and D-fructose to form Cr(III)-saccharide complexes via an intermediate Cr(V) species. These saccharide complexes have been isolated in the solid state for the first time and characterized by analytical, spectroscopic, magnetic and electrochemical methods. Bridged dinuclear saccharide complexes of Cr(III) have been proposed.
 
Publisher ELSEVIER SCIENCE BV
 
Date 2011-07-24T13:05:31Z
2011-12-26T12:55:47Z
2011-12-27T05:42:27Z
2011-07-24T13:05:31Z
2011-12-26T12:55:47Z
2011-12-27T05:42:27Z
1992
 
Type Article
 
Identifier CARBOHYDRATE RESEARCH, 237(), 195-202
0008-6215
http://dspace.library.iitb.ac.in/xmlui/handle/10054/6432
http://hdl.handle.net/10054/6432
 
Language en