Tuning the dispersion of multiwall carbon nanotubes in co-continuous polymer blends: a generic approach
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Title |
Tuning the dispersion of multiwall carbon nanotubes in co-continuous polymer blends: a generic approach
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Creator |
BOSE, S
BHATTACHARYYA, AR KHARE, RA KULKARNI, AR PATRO, TU SIVARAMAN, P |
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Subject |
nanocomposites
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Description |
Melt-mixed blends of polyamide 6 and acrylonitrile-butadiene-styrene (PA6/ABS) with multiwall carbon nanotubes (MWNTs) were prepared with the intention to develop conducting composites. A generic strategy, namely specific interactions combined with reactive coupling, was adopted to facilitate and to retain the 'network-like' structure of MWNTs during melt-mixing. This was facilitated by the sodium salt of 6-amino hexanoic acid (Na-AHA) and certain phosphonium based modifiers, where it was envisaged that these modifiers would establish specific interactions (either 'cation-pi' or 'pi-pi') with the 'pi-electron' clouds of MWNTs, as well as restricting them in the PA6 phase of the blends via reactive coupling. This route eventually led to a remarkable increase in the electrical conductivity and dielectric constant in the blends with MWNTs. Raman, FTIR and TEM investigations further supported these observations.
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Publisher |
IOP PUBLISHING LTD
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Date |
2011-08-04T02:44:05Z
2011-12-26T12:54:31Z 2011-12-27T05:42:28Z 2011-08-04T02:44:05Z 2011-12-26T12:54:31Z 2011-12-27T05:42:28Z 2008 |
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Type |
Article
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Identifier |
NANOTECHNOLOGY, 19(33), -
0957-4484 http://dx.doi.org/10.1088/0957-4484/19/33/335704 http://dspace.library.iitb.ac.in/xmlui/handle/10054/9221 http://hdl.handle.net/10054/9221 |
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Language |
en
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