Record Details

An unusual cyclopentaannulation reaction: Thermolysis of an alpha,beta-unsaturated Fischer carbene complex anchored on a Fe-2(CO)(6)(mu-Se)(2) core

DSpace at IIT Bombay

View Archive Info
 
 
Field Value
 
Title An unusual cyclopentaannulation reaction: Thermolysis of an alpha,beta-unsaturated Fischer carbene complex anchored on a Fe-2(CO)(6)(mu-Se)(2) core
 
Creator MATHUR, P
GHOSH, S
SARKAR, A
RHEINGOLD, AL
GUZEI, IA
 
Subject acetylenic bond reduction
selenium complexes
crystal-structure
fe2(co)6(mu-se2)
insertion
 
Description An unusual annulation of-a Fischer carbene complex anchored on a Fe-2(CO)(6)(mu-Se)(2) core is examined. Thermolysis of Fe-2(CO)(6){mu-SeC(Ph)=C(Se)[(OEt)C=Cr(CO)(5)]} in THF yields an unusual annulated product, [Fe-2(CO)(6)Se-2{mu-(CO)(3)Cr(eta(5)-C5H(CH2Ph)(Ph)(OEt))}] (1), as characterized by IR and H-1, C-13, and Se-77 NMR spectroscopies, and its structure has been established by single-crystal X-ray diffraction.
 
Publisher AMER CHEMICAL SOC
 
Date 2011-07-13T16:23:58Z
2011-12-26T12:47:58Z
2011-12-27T05:42:40Z
2011-07-13T16:23:58Z
2011-12-26T12:47:58Z
2011-12-27T05:42:40Z
1998
 
Type Article
 
Identifier ORGANOMETALLICS, 17(4), 770-772
0276-7333
http://dx.doi.org/10.1021/om9708182
http://dspace.library.iitb.ac.in/xmlui/handle/10054/3718
http://hdl.handle.net/10054/3718
 
Language en