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Reductive cleavage of azo dyes and reduction of nitroarenes over trivalent iron incorporated hexagonal mesoporous aluminophosphate molecular sieves

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Title Reductive cleavage of azo dyes and reduction of nitroarenes over trivalent iron incorporated hexagonal mesoporous aluminophosphate molecular sieves
 
Creator MOHAPATRA, SK
SONAVANE, SU
JAYARAM, RV
SELVAM, P
 
Subject catalytic transfer hydrogenation
meerwein-ponndorf-verley
oxide hydroxide catalyst
aromatic nitro-compounds
hydrazine hydrate
heterogeneous catalysts
nitroaromatic compounds
oppenauer reactions
carbonyl-compounds
organic-compounds
azo dyes
nitroarenes
catalytic transfer hydrogenation
fehma
mesoporous molecular sieves
aluminophosphates
 
Description A novel, efficient and eco-friendly iron incorporated hexagonal mesoporous aluminiphosphate (FeHMA) catalyst is put forward for the reductive cleavage of azo functions as well as for the reduction of nitroarenes, including larger molecules, by catalytic transfer hydrogenation (CTH). The results indicate that the transformations occur in elegant and rapid manner with excellent yields. Furthermore, the catalyst can easily be recovered and reused without practically affecting the yields for up to six cycles. (C) 2003
 
Publisher ELSEVIER SCIENCE BV
 
Date 2011-07-26T13:38:59Z
2011-12-26T12:54:36Z
2011-12-27T05:42:41Z
2011-07-26T13:38:59Z
2011-12-26T12:54:36Z
2011-12-27T05:42:41Z
2003
 
Type Article
 
Identifier APPLIED CATALYSIS B-ENVIRONMENTAL, 46(1), 155-163
0926-3373
http://dx.doi.org/10.1016/S0926-3373(03)00182-6
http://dspace.library.iitb.ac.in/xmlui/handle/10054/6918
http://hdl.handle.net/10054/6918
 
Language en