Record Details

LOW-PRESSURE POLYMERIZATION OF ETHYLENE .2.

DSpace at IIT Bombay

View Archive Info
 
 
Field Value
 
Title LOW-PRESSURE POLYMERIZATION OF ETHYLENE .2.
 
Creator PANDYA, MV
LATA, KV
 
Description This paper presents the kinetic study of polymerization of ethylene with VOCl3 and aluminum alkyls such as Et3Al and Et2AlCl. The effect of various parameters like the [Al]/[V] ratio, catalyst concentration, reaction time, temperature, solvents, and additives on rate of the reaction, yield, and molecular weight is reported. Each of these parameters has a remarkable effect on the yield and the rate of polymerization for both catalyst systems. Triethylamine is found to increase the catalyst efficiency and the rate. It is also observed that aliphatic hydrocarbons acted as a better polymerization medium than did the aromatic ones.
 
Publisher JOHN WILEY & SONS INC
 
Date 2011-08-16T08:32:42Z
2011-12-26T12:54:50Z
2011-12-27T05:43:10Z
2011-08-16T08:32:42Z
2011-12-26T12:54:50Z
2011-12-27T05:43:10Z
1991
 
Type Article
 
Identifier JOURNAL OF APPLIED POLYMER SCIENCE, 43(4), 637-642
0021-8995
http://dx.doi.org/10.1002/app.1991.070430402
http://dspace.library.iitb.ac.in/xmlui/handle/10054/9443
http://hdl.handle.net/10054/9443
 
Language en